# Entropy equation

### From Thermal-FluidsPedia

To obtain the differential form of the second law of thermodynamics, the surface integrals in eq. from Integral entropy equation can be rewritten as volume integrals:

Substituting eqs. (1) and (2) into eq. and considering eq. from Continuity equation yields

In order for eq. (3) to be true for any arbitrary control volume, the integrand in eq. (3) should always be positive, i.e.,

Equation (4) can be rewritten as

Considering the continuity equation, eq. from Conservation of mass species equation, and definition of the substantial derivative, eq. from Conservation of mass species equation, eq. (5) can be reduced to

where the three terms on the left-hand side represent rate of change of entropy per unit volume, rate of change of entropy per unit volume by heat transfer and internal heat generation, respectively. Equation (6) means that the entropy generation per unit volume must not be negative at any time or location.

For a multicomponent system without internal heat generation (*q*''' = 0), Curtiss and Bird (1999; 2001) obtained the entropy flux vector and the entropy generation as

where *d*_{i} is the diffusional driving force [see eq. (2) – (6)], is partial molar Gibbs free energy, is total heat flux, obtained by eq. **Failed to parse (unknown function\rlap): {\mathbf{q''}} = - k\nabla T + \sum\limits_{i = 1}^N {{h_i}{{\mathbf{J}}_i}} + c{R_u}T\sum\limits_{i = 1}^N {\frac{{{x_i}{x_j}}}{{{\rho _i}}}\frac{{D_i^T}}{{{{\rlap{--} D}_{ij}}}}} \left( {\frac{{{{\mathbf{J}}_i}}}{{{\rho _i}}} - \frac{{{{\mathbf{J}}_j}}}{{{\rho _j}}}} \right)**

from Energy equation, including conduction, interdiffusional convection, and Dufour effect.

## References

Curtiss, C.F., and Bird, R.B., 1999, “Multicomponent Diffusion,” *Industrial and Engineering Chemistry Research*, Vol. 38, pp. 2115-2522.

Curtiss, C.F., and Bird, R.B., 2001, “Errata,” *Industrial and Engineering Chemistry Research*, Vol. 40, p. 1791.