Governing equations for natural convection
From ThermalFluidsPedia
The governing equations for natural convection are special cases of the generalized governing equations that were discussed in Chapter 2. Consider a multicomponent system with N components, the governing equations for a stationary reference frame can be expressed as


where the viscous stress tensor, τ, can be determined by using Newton’s law of viscosity:

where D is the rate of strain tensor:

For natural convection problems, it is often assumed that the fluid is incompressible, except in the first term on the righthand side of eq. (2); this is referred to as the Boussinesq assumption. Under this assumption, the continuity equation (1) becomes:

According to eq. (5), the second term on the righthand side of eq. (3) will be zero. The momentum equation (2) then becomes:

where the lefthand side is the inertial term; the three terms on the righthand side represent body force per unit volume, pressure force per unit volume, and viscous force per unit volume, respectively.
The density of a mixture is a function of its temperature and the mass fractions of its species. It can be expanded using a Taylor’s series near the vicinity of a reference point ():

where is density at the reference point. By defining the coefficient of thermal expansion, β, and composition coefficient of volume expansion, β_{m},i, as follows:
and neglecting the higher order terms in the Taylor’s series expansion, one obtains:

which is valid only if
Substituting eq. (9) into eq. (6), the momentum equation for natural convection is obtained:

which is a generalized momentum equation because the effects of buoyancy forces due to both temperature and composition variations are considered.
If it is assumed that the Dufour effect is negligible and the fluid is incompressible, the energy equation is:

The conservation of species mass in terms of mass fraction for the ith species can be expressed as

For a binary system of A and B, one can apply Fick’s law to eq. (12) to obtain:

References
Faghri, A., Zhang, Y., and Howell, J. R., 2010, Advanced Heat and Mass Transfer, Global Digital Press, Columbia, MO.